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Strategy for contra-thermodynamic radical-chain epimerisation of 1,2-diols using polarity-reversal catalysis

Dang, HS; Roberts, BP; (2000) Strategy for contra-thermodynamic radical-chain epimerisation of 1,2-diols using polarity-reversal catalysis. Tetrahedron Letters , 41 (44) 8595 - 8599.

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Abstract

Polarity-reversal catalysis by thiols has been applied to provide an efficient method for the conversion of appropriate 1,2-diols into less or similarly stable diastereoisomers by epimerisation of their acetonides under radical-chain conditions. (C) 2000 Elsevier Science Ltd. All rights reserved

Type:Article
Title:Strategy for contra-thermodynamic radical-chain epimerisation of 1,2-diols using polarity-reversal catalysis
Additional information:Journal Article OCT 28 370YE Roberts BP Univ Coll London, Dept Chem, 20 Gordon St, London WC1H 0AJ, England TETRAHEDRON LETT
Keywords:ATOM ABSTRACTION, carbohydrates, Catalysis, CONVERSION, diols, isomerisation, radicals and radical reactions, Science, strategies, strategy, TERT-BUTOXYL RADICALS, thiols, TRAPPING TECHNIQUE
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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