Dang, HS and Franchi, P and Roberts, BP (2000) Radical-chain deoxygenation of tertiary alcohols, protected as their methoxymethyl (MOM) ethers, using thiols as polarity- reversal catalysts. Chemical Communications (6) 499 - 500.
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Abstract
The deoxygenation of tertiary alcohols can be accomplished by heating their MOM ethers in the presence of a peroxide initiator and a thiol catalyst: the proposed radical-chain mechanism is supported by EPR spectroscopic studies
| Type: | Article |
|---|---|
| Title: | Radical-chain deoxygenation of tertiary alcohols, protected as their methoxymethyl (MOM) ethers, using thiols as polarity- reversal catalysts |
| Additional information: | Journal Article 292YA Roberts BP Univ London Univ Coll, Dept Chem, Christopher Ingold Labs, 20 Gordon St, London WC1H 0AJ, England CHEM COMMUN |
| Keywords: | Alcohol, ALCOHOLS, As, CATALYSTS, ELECTRON-SPIN RESONANCE, EPR, MECHANISM, thiols |
| UCL classification: | UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry |
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