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Clusters containing metal-metal bonds linking high- and low-valent metal centres: synthesis and structure of Ru-3(CO)(12){Mo(NAr)(2)}

Ali, S; Carty, AJ; Deeming, AJ; Enright, GD; Hogarth, G; (2000) Clusters containing metal-metal bonds linking high- and low-valent metal centres: synthesis and structure of Ru-3(CO)(12){Mo(NAr)(2)}. CHEM COMMUN (2) 123 - 124.

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Abstract

Room temperature reaction of K-2[Ru-3(CO)(11)] with the molybdenum(VI) bis(imido) complexes Mo(NAr)(2)Cl-2(dme) (Ar = C6H3X2-2,6; X = Me, Pr-i, Cl; dme = 1,2-dimethoxyethane) affords new high-low valent clusters Ru-3(CO)(12){Mo(NAr)(2)} which adopt a butterfly arrangement of metal centres with [Ru-3(CO)(12)](2-) acting as a ligand at a molybdenum(VI) centre.

Type:Article
Title:Clusters containing metal-metal bonds linking high- and low-valent metal centres: synthesis and structure of Ru-3(CO)(12){Mo(NAr)(2)}
Keywords:BIS(IMIDO) ALKENE COMPLEXES, IMIDO, MOLYBDENUM, LIGAND, PHENYLIMIDO, MODELS
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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