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Metal-catalysed Halogen Exchange Reactions of Aryl Halides

Sheppard, TD; (2009) Metal-catalysed Halogen Exchange Reactions of Aryl Halides. Organic and Biomolecular Chemistry , 7 1043 - 1052. 10.1039/B818155A. Green open access

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Abstract

Aryl halides are common synthetic targets themselves, and also highly versatile synthetic intermediates. Aryl chlorides are much more widely available and easier to synthesise than the other halide derivatives, so the development of effective methods for interconverting aryl halide derivatives would therefore be extremely useful. This article outlines which transformations are particularly desirable, and describes the progress that has been made on developing methods for carrying out those transformations using copper, nickel or palladium catalysts. The possible mechanisms of these reactions are discussed, with a view to identifying areas for future investigation.

Type: Article
Title: Metal-catalysed Halogen Exchange Reactions of Aryl Halides
Location: UK
Open access status: An open access version is available from UCL Discovery
DOI: 10.1039/B818155A
Publisher version: http://dx.doi.org/10.1039/B818155A
Language: English
Additional information: Sheppard, TD (2009) Metal-catalysed Halogen Exchange Reactions of Aryl Halides. Organic and Biomolecular Chemistry , 7 1043-1052 – Reproduced by permission of The Royal Society of Chemistry
UCL classification: UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry
URI: http://discovery.ucl.ac.uk/id/eprint/170129
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