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Non-alpha-hydroxylated aldehydes with evolved transketolase enzymes

Cazares, A; Galman, JL; Crago, LG; Smith, MEB; Strafford, J; Rios-Solis, L; ... Hailes, HC; + view all (2010) Non-alpha-hydroxylated aldehydes with evolved transketolase enzymes. ORG BIOMOL CHEM , 8 (6) 1301 - 1309. 10.1039/b924144b.

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Abstract

Transketolase mutants previously identified for use with the non-phosphorylated aldehyde propanal have been explored with a series of linear and cyclic aliphatic aldehydes, and excellent stereoselectivities observed.

Type:Article
Title:Non-alpha-hydroxylated aldehydes with evolved transketolase enzymes
DOI:10.1039/b924144b
Keywords:ESCHERICHIA-COLI TRANSKETOLASE, ENZYMATIC THIAMIN CATALYSIS, CARBON BOND FORMATION, BIOCATALYTIC SYNTHESIS, SUBSTRATE-SPECIFICITY, XYLULOSE 5-PHOSPHATE, DIRECTED EVOLUTION, AMINO-ALCOHOLS, TRANSAMINASE, DIPHOSPHATE
UCL classification:UCL > School of BEAMS > Faculty of Engineering Science > Biochemical Engineering
UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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