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ENANTIOSELECTIVE SYNTHESIS OF (S)-GAMMA-ACETYLENIC GAMMA-AMINOBUTYRIC-ACID (GABA)

HOLMES, AB; TABOR, AB; BAKER, R; (1991) ENANTIOSELECTIVE SYNTHESIS OF (S)-GAMMA-ACETYLENIC GAMMA-AMINOBUTYRIC-ACID (GABA). J CHEM SOC PERK T 1 (12) 3301 - 3306.

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Abstract

The enantioselective synthesis of (S)-gamma-acetylenic gamma-aminobutyric acid (GABA) 1 by phthalimide displacement of the (R)-prop-2-ynylic alcohol 12 (generated from acetal 4) is reported.

Type:Article
Title:ENANTIOSELECTIVE SYNTHESIS OF (S)-GAMMA-ACETYLENIC GAMMA-AMINOBUTYRIC-ACID (GABA)
Keywords:ASYMMETRIC-SYNTHESIS, ACETAL TEMPLATES, ENKEPHALIN ANALOG, PEPTIDE-BOND, STEREOCHEMISTRY, DERIVATIVES, ALCOHOLS, SILICON, OXYGEN
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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