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Effect of peptide orientation on electron transfer

Chaudhry, BR; Wilton-Ely, JDET; Tabor, AB; Caruana, DJ; (2010) Effect of peptide orientation on electron transfer. PHYS CHEM CHEM PHYS , 12 (34) 9996 - 9998. 10.1039/c0cp00226g.

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Abstract

We have developed a methodology for the in situ derivatisation of histidine residues in self-assembled monolayers of peptides with redox-active groups, and have shown by electrochemical methods that the average dipole of peptide films on gold affects the heterogeneous electron transfer properties.

Type:Article
Title:Effect of peptide orientation on electron transfer
DOI:10.1039/c0cp00226g
Keywords:ALKANETHIOL MONOLAYERS, DISTANCE DEPENDENCE, TRANSFER KINETICS, HELICAL PEPTIDES, FERROCENE, GOLD
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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