Chudasama, V;
(2015)
Pentafluorophenyl vinyl sulfonate enables efficient, metal-free, radical-based alkene hydroacylation with an aldehyde as a limiting reagent.
RSC Advances
, 5
(55)
pp. 44423-44426.
10.1039/c5ra08353b.
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Abstract
The unique properties of pentafluorophenyl vinyl sulfonate allow for a hitherto unmet feat to be realised; efficient and high yielding, metal-free, radical-based alkene hydroacylation employing aldehyde as limiting reagent. The optimised conditions are shown to work in good yields across a series of aldehydes, thus demonstrating the wide applicability of the developed protocol.
| Type: | Article |
|---|---|
| Title: | Pentafluorophenyl vinyl sulfonate enables efficient, metal-free, radical-based alkene hydroacylation with an aldehyde as a limiting reagent |
| Open access status: | An open access version is available from UCL Discovery |
| DOI: | 10.1039/c5ra08353b |
| Publisher version: | http://dx.doi.org/10.1039/c5ra08353b |
| Language: | English |
| Additional information: | © The Royal Society of Chemistry 2015 |
| UCL classification: | UCL UCL > Provost and Vice Provost Offices UCL > Provost and Vice Provost Offices > UCL BEAMS UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry |
| URI: | https://discovery.ucl.ac.uk/id/eprint/1473854 |
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