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Studies on the oxidation and fluorination of alpha-phenylsulfanylacetamides using difluoroiodotoluene

Greaney, MF; Motherwell, WB; (2000) Studies on the oxidation and fluorination of alpha-phenylsulfanylacetamides using difluoroiodotoluene. TETRAHEDRON LETT , 41 (22) 4467 - 4470.

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Abstract

alpha-Phenylsulfanylacetamides are fluorinated in the alpha-position when treated with difluoroiodotoluene (DFIT) in a fluoro-Pummerer reaction. For N-phenyl amides an intramolecular Friedel-Crafts reaction may compete and produce heterocycles. (C) 2000 Elsevier Science Ltd. All rights reserved.

Type:Article
Title:Studies on the oxidation and fluorination of alpha-phenylsulfanylacetamides using difluoroiodotoluene
Keywords:halogenation, oxidation, fluorine and compounds, hypervalent elements
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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