Studies on the oxidation and fluorination of alpha-phenylsulfanylacetamides using difluoroiodotoluene.
4467 - 4470.
alpha-Phenylsulfanylacetamides are fluorinated in the alpha-position when treated with difluoroiodotoluene (DFIT) in a fluoro-Pummerer reaction. For N-phenyl amides an intramolecular Friedel-Crafts reaction may compete and produce heterocycles. (C) 2000 Elsevier Science Ltd. All rights reserved.
|Title:||Studies on the oxidation and fluorination of alpha-phenylsulfanylacetamides using difluoroiodotoluene|
|Keywords:||halogenation, oxidation, fluorine and compounds, hypervalent elements|
|UCL classification:||UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry|
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