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Observations on the alpha-fluorination of alpha-phenylsulfanyl esters using difluoroiodotoluene

Greaney, MF; Motherwell, WB; (2000) Observations on the alpha-fluorination of alpha-phenylsulfanyl esters using difluoroiodotoluene. TETRAHEDRON LETT , 41 (22) 4463 - 4466.

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Abstract

alpha-Phenylsulfanyl esters are fluorinated in the alpha-position when treated with the hypervalent iodine reagent difluoroiodotoluene. Excess reagent can lead to alpha-fluoro sulfoxides, which can then undergo thermal syn elimination to produce vinyl fluorides. (C) 2000 Elsevier Science Ltd. All rights reserved.

Type:Article
Title:Observations on the alpha-fluorination of alpha-phenylsulfanyl esters using difluoroiodotoluene
Keywords:halogenation, hypervalent elements, fluorine and compounds, FLUORO THIOETHERS, (DIETHYLAMINO)SULFUR TRIFLUORIDE, OXIDATIVE-FLUORINATION, ANTIMONY(III) CHLORIDE, XENON DIFLUORIDE, SULFIDES, ANALOGS, 4-METHYL(DIFLUOROIODO)BENZENE, CONVERSION, SULFOXIDES
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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