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INTRAMOLECULAR PALLADIUM-CATALYZED [3+2] CYCLOADDITIONS OF METHYLENECYCLOPROPANES WITH ACETYLENIC ACCEPTORS

CORLAY, H; LEWIS, RT; MOTHERWELL, WB; SHIPMAN, M; (1995) INTRAMOLECULAR PALLADIUM-CATALYZED [3+2] CYCLOADDITIONS OF METHYLENECYCLOPROPANES WITH ACETYLENIC ACCEPTORS. TETRAHEDRON , 51 (11) 3303 - 3318.

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Abstract

The synthesis and intramolecular palladium catalysed cycloaddition reactions of eight methylenecyclopropanes containing alkyne accepters are described. Bicyclo[3.3.0]octane and bicyclo[4.3.0]nonane rings systems can be successfully accessed using this chemistry. The nature of the substituents attached to the alkyne acceptor play a key role in the efficiency of the cycloaddition.

Type:Article
Title:INTRAMOLECULAR PALLADIUM-CATALYZED [3+2] CYCLOADDITIONS OF METHYLENECYCLOPROPANES WITH ACETYLENIC ACCEPTORS
Keywords:TRIMETHYLENEMETHANE CYCLOADDITIONS, CYCLO-ADDITION
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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