CORLAY, H and LEWIS, RT and MOTHERWELL, WB and SHIPMAN, M (1995) INTRAMOLECULAR PALLADIUM-CATALYZED [3+2] CYCLOADDITIONS OF METHYLENECYCLOPROPANES WITH ACETYLENIC ACCEPTORS. TETRAHEDRON , 51 (11) 3303 - 3318.
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Abstract
The synthesis and intramolecular palladium catalysed cycloaddition reactions of eight methylenecyclopropanes containing alkyne accepters are described. Bicyclo[3.3.0]octane and bicyclo[4.3.0]nonane rings systems can be successfully accessed using this chemistry. The nature of the substituents attached to the alkyne acceptor play a key role in the efficiency of the cycloaddition.
| Type: | Article |
|---|---|
| Title: | INTRAMOLECULAR PALLADIUM-CATALYZED [3+2] CYCLOADDITIONS OF METHYLENECYCLOPROPANES WITH ACETYLENIC ACCEPTORS |
| Keywords: | TRIMETHYLENEMETHANE CYCLOADDITIONS, CYCLO-ADDITION |
| UCL classification: | UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry |
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