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Gold catalysed synthesis of 3-alkoxyfurans at room temperature

Pennell, MN; Foster, RW; Turner, PG; Hailes, HC; Tame, CJ; Sheppard, TD; (2014) Gold catalysed synthesis of 3-alkoxyfurans at room temperature. Chemical Communications , 50 (11) 1302 - 1304. 10.1039/c3cc48290a. Green open access

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Abstract

Synthetically important 3-alkoxyfurans can be prepared efficiently via treatment of acetal-containing propargylic alcohols (obtained from the addition of 3,3-diethoxypropyne to aldehydes) with 2 mol% gold catalyst in an alcohol solvent at room temperature. The resulting furans show useful reactivity in a variety of subsequent transformations.

Type: Article
Title: Gold catalysed synthesis of 3-alkoxyfurans at room temperature
Open access status: An open access version is available from UCL Discovery
DOI: 10.1039/c3cc48290a
Publisher version: http://dx.doi.org/10.1039/c3cc48290a
Language: English
Additional information: This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0).
UCL classification: UCL > Provost and Vice Provost Offices
UCL > Provost and Vice Provost Offices > UCL BEAMS
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences
UCL > Provost and Vice Provost Offices > UCL BEAMS > Faculty of Maths and Physical Sciences > Dept of Chemistry
URI: http://discovery.ucl.ac.uk/id/eprint/1418043
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