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Neptunium(VI) chain and neptunium(VI/V) mixed valence cluster complexes

Cornet, SM; Haller, LJL; Sarsfield, MJ; Collison, D; Helliwell, M; May, I; Kaltsoyannis, N; (2009) Neptunium(VI) chain and neptunium(VI/V) mixed valence cluster complexes. CHEM COMMUN (8) 917 - 919. 10.1039/b818973k.

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Abstract

The synthesis of [(NpO2Cl2)-O-VI(thf)](n) offers the potential for more detailed exploration of neptunyl(VI) chemistry, while the synthesis of the mixed valence cluster complex[{(NpO2Cl2)-O-VI}{(NpO2Cl)-O-V(thf)(3)}(2)] allows molecular neptunyl(V) 'cation-cation' interactions to be probed.

Type:Article
Title:Neptunium(VI) chain and neptunium(VI/V) mixed valence cluster complexes
DOI:10.1039/b818973k
Keywords:CATION-CATION INTERACTIONS, CRYSTAL-STRUCTURE, EQUATORIAL COORDINATION, MOLECULAR-STRUCTURES, NEPTUNYL CHLORIDE, URANYL, CHEMISTRY, DISPROPORTIONATION, ABSORPTION, REDUCTION
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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