Cornet, SM and Haller, LJL and Sarsfield, MJ and Collison, D and Helliwell, M and May, I and Kaltsoyannis, N (2009) Neptunium(VI) chain and neptunium(VI/V) mixed valence cluster complexes. CHEM COMMUN (8) 917 - 919. 10.1039/b818973k.
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Abstract
The synthesis of [(NpO2Cl2)-O-VI(thf)](n) offers the potential for more detailed exploration of neptunyl(VI) chemistry, while the synthesis of the mixed valence cluster complex[{(NpO2Cl2)-O-VI}{(NpO2Cl)-O-V(thf)(3)}(2)] allows molecular neptunyl(V) 'cation-cation' interactions to be probed.
| Type: | Article |
|---|---|
| Title: | Neptunium(VI) chain and neptunium(VI/V) mixed valence cluster complexes |
| DOI: | 10.1039/b818973k |
| Keywords: | CATION-CATION INTERACTIONS, CRYSTAL-STRUCTURE, EQUATORIAL COORDINATION, MOLECULAR-STRUCTURES, NEPTUNYL CHLORIDE, URANYL, CHEMISTRY, DISPROPORTIONATION, ABSORPTION, REDUCTION |
| UCL classification: | UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry |
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