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Liquid-mediated metathetical synthesis of binary and ternary transition-metal pnictides

Carmalt, CJ; Morrison, DE; Parkin, IP; (2000) Liquid-mediated metathetical synthesis of binary and ternary transition-metal pnictides. POLYHEDRON , 19 (7) 829 - 833.

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Abstract

Nickel and cobalt pnictides have been synthesised using a liquid-mediated metathetical reaction of transition-metal dihalides with the appropriate sodium pnictide Na3E (E=P, As, Sb) in refluxing toluene for 48 h. Binary and ternary compounds have been prepared. Products were analysed by powder X-ray diffraction, scanning electron microscopy, energy dispersive analysis by X-rays, FT-IR, Raman and vibrating sample magnetometry. (C) 2000 Elsevier Science Ltd All rights reserved.

Type:Article
Title:Liquid-mediated metathetical synthesis of binary and ternary transition-metal pnictides
Keywords:antimonides, arsenides, metathesis, phosphides, CHEMICAL-VAPOR-DEPOSITION, NICKEL-PHOSPHORUS, THIN-FILMS, NIP, MULTILAYERS, PHOSPHIDE, ALLOYS
UCL classification:UCL > School of Life and Medical Sciences > Faculty of Brain Sciences > Institute of Neurology > IoN - Neuroinflammation
UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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