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SYNTHESIS AND CERTAIN TRANSFORMATIONS OF GAMMA-NITROSOALCOHOLS

RUDCHENKO, VF; CHERVIN, II; ALIEV, AE; KOSTYANOVSKII, RG; (1991) SYNTHESIS AND CERTAIN TRANSFORMATIONS OF GAMMA-NITROSOALCOHOLS. B ACAD SCI USSR CH+ , 40 (7) 1380 - 1386.

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Abstract

The gamma-nitrosoalcohols (II), (XII), and (IX), respectively, have been synthesized by acid-catalyzed hydrolysis of 2-alkoxyisoxazolidines (I), (Xa, b), (Xla, b), and 3-(dimethoxyamino)-3-trifluoromethylbutanol-1 (VIII). The nitrosoalcohol (II) readily rearranges into the oxime (III), and (XII) is converted into the diol (XIII) by oxidation with atmospheric O2 and denitrosation. For (IX) and (XII) ring-chain tautomerism with formation of 2-hydroxyisoxazolidines could not be detected by PMR spectroscopy.

Type:Article
Title:SYNTHESIS AND CERTAIN TRANSFORMATIONS OF GAMMA-NITROSOALCOHOLS
Keywords:NITROGEN
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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