SYNTHESIS AND CERTAIN TRANSFORMATIONS OF GAMMA-NITROSOALCOHOLS.
B ACAD SCI USSR CH+
1380 - 1386.
The gamma-nitrosoalcohols (II), (XII), and (IX), respectively, have been synthesized by acid-catalyzed hydrolysis of 2-alkoxyisoxazolidines (I), (Xa, b), (Xla, b), and 3-(dimethoxyamino)-3-trifluoromethylbutanol-1 (VIII). The nitrosoalcohol (II) readily rearranges into the oxime (III), and (XII) is converted into the diol (XIII) by oxidation with atmospheric O2 and denitrosation. For (IX) and (XII) ring-chain tautomerism with formation of 2-hydroxyisoxazolidines could not be detected by PMR spectroscopy.
|Title:||SYNTHESIS AND CERTAIN TRANSFORMATIONS OF GAMMA-NITROSOALCOHOLS|
|UCL classification:||UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry|
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