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A facile synthesis of dibenzopyrroloazepinones as tetracyclic allocolchicinoids-an unusual 1,2-phenyl shift

Wu, L; Aliev, AE; Caddick, S; Fitzmaurice, RJ; Tocher, DA; King, FD; (2010) A facile synthesis of dibenzopyrroloazepinones as tetracyclic allocolchicinoids-an unusual 1,2-phenyl shift. CHEM COMMUN , 46 (2) 318 - 320. 10.1039/b919114c.

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Abstract

A facile synthesis of dibenzopyrroloazepinones via an electrophilic cyclisation of a biphenyl-acyliminium ion is described; an unusual 1,2-phenyl shift occurs when the C-1' carbon is the more nucleophilic than the C-2' carbon.

Type:Article
Title:A facile synthesis of dibenzopyrroloazepinones as tetracyclic allocolchicinoids-an unusual 1,2-phenyl shift
DOI:10.1039/b919114c
Keywords:DERIVATIVES
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry
UCL > VP Enterprise

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