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Structure and Reactivity of Aluminum Oxide Supported Nickel Clusters

Briquet, LGV; Catlow, CRA; French, SA; (2010) Structure and Reactivity of Aluminum Oxide Supported Nickel Clusters. J PHYS CHEM C , 114 (50) 22155 - 22158. 10.1021/jp101710v.

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Abstract

We present the results of a computational study, based on density functional theory, of CO with oxide-supported Ni atom and cluster. Our results reveal effective adsorption sites at the cluster oxide interface and show how the oxide assists the activation of the adsorbed CO.

Type: Article
Title: Structure and Reactivity of Aluminum Oxide Supported Nickel Clusters
DOI: 10.1021/jp101710v
Keywords: TEMPERATURE-PROGRAMMED DESORPTION, CO ADSORPTION, INFRARED-SPECTROSCOPY, CARBON-MONOXIDE, PALLADIUM CATALYSTS, HYDROGEN-PRODUCTION, NI/AL2O3 CATALYST, METAL-CLUSTERS, SURFACES, HEATS
UCL classification: UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry
URI: http://discovery.ucl.ac.uk/id/eprint/1366270
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