MARSON, CM and HARPER, S and WALKER, AJ and PICKERING, J and CAMPBELL, J and WRIGGLESWORTH, R and EDGE, SJ (1993) LEWIS-ACID MEDIATED REACTIONS OF 2,3-EPOXYALCOHOLS - AN EFFICIENT STEREOCONTROLLED ROUTE TO POLYCYCLIC DIOLS. TETRAHEDRON , 49 (45) 10339 - 10354.
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Abstract
2,3-epoxyalcohols are shown to undergo stereoselective reactions in the presence of tin tetrachloride. The resulting diols when treated with acid are converted into polycyclic aromatic hydrocarbons or polycyclic ketones.
| Type: | Article |
|---|---|
| Title: | LEWIS-ACID MEDIATED REACTIONS OF 2,3-EPOXYALCOHOLS - AN EFFICIENT STEREOCONTROLLED ROUTE TO POLYCYCLIC DIOLS |
| Keywords: | HYDROXYLATED TRICYCLIC SYSTEMS, CARBONYL-COMPOUNDS, EPOXIDES, ALCOHOLS, 2-CYCLOHEXEN-1-ONE, REARRANGEMENTS, ANNULATION |
| UCL classification: | UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry |
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