Raynor, SA and Thomas, JM and Raja, R and Johnson, BFG and Bell, RG and Mantle, MD (2000) A one-step, enantioselective reduction of ethyl nicotinate to ethyl nipecotinate using a constrained, chiral, heterogeneous catalyst. CHEM COMMUN (19) 1925 - 1926.
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Abstract
A chiral catalyst derived from 1,1'-bis(diphenylphosphino)ferrocene and anchored within MCM-41 displays remarkable increases in both enantioselectivity and activity, in the hydrogenation of ethyl nicotinate to ethyl nipecotinate, when compared to an analogous homogeneous model compound.
| Type: | Article |
|---|---|
| Title: | A one-step, enantioselective reduction of ethyl nicotinate to ethyl nipecotinate using a constrained, chiral, heterogeneous catalyst |
| Keywords: | MESOPOROUS SILICA, RESOLUTION, AROMATICS, COMPLEXES, SITE |
| UCL classification: | UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry |
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