Raynor, SA and Thomas, JM and Raja, R and Johnson, BFG and Bell, RG and Mantle, MD (2000) A one-step, enantioselective reduction of ethyl nicotinate to ethyl nipecotinate using a constrained, chiral, heterogeneous catalyst. CHEM COMMUN (19) 1925 - 1926.
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A chiral catalyst derived from 1,1'-bis(diphenylphosphino)ferrocene and anchored within MCM-41 displays remarkable increases in both enantioselectivity and activity, in the hydrogenation of ethyl nicotinate to ethyl nipecotinate, when compared to an analogous homogeneous model compound.
|Title:||A one-step, enantioselective reduction of ethyl nicotinate to ethyl nipecotinate using a constrained, chiral, heterogeneous catalyst|
|Keywords:||MESOPOROUS SILICA, RESOLUTION, AROMATICS, COMPLEXES, SITE|
|UCL classification:||UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry|
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