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beta-Diketiminate C-H activation with heavier group 2 alkyls

Crimmin, MR; Barrett, AGM; Hill, MS; MacDougall, DJ; Mahon, MF; Procopiou, PA; (2009) beta-Diketiminate C-H activation with heavier group 2 alkyls. DALTON T (44) 9715 - 9717. 10.1039/b917466b.

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Abstract

Well defined dialkyls of the heavier alkaline earth elements, [M{CH(SiMe3)(2)}(2)(THF)(n)] [M = Ca, n = 2; M = Sr, n = 3; M = Ba, n = 3] react to form either the heteroleptic beta-diketiminato alkyl when M = Ca or unusual 'C-H activation' products in which a methyl group of the ligand is deprotonated when M = Sr or Ba.

Type:Article
Title:beta-Diketiminate C-H activation with heavier group 2 alkyls
DOI:10.1039/b917466b
Keywords:SIGMA-BOND METATHESIS, COMPLEXES, DEPROTONATION, STRONTIUM, LIGANDS, BARIUM
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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