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Atmospheric pressure chemical vapour deposition of tin(II) sulfide films on glass substrates from (Bu3SnO2CCF3)-Sn-n with hydrogen sulfide

Price, LS and Parkin, IP and Field, MN and Hardy, AME and Clark, RJH and Hibbert, TG and Molloy, KC (2000) Atmospheric pressure chemical vapour deposition of tin(II) sulfide films on glass substrates from (Bu3SnO2CCF3)-Sn-n with hydrogen sulfide. J MATER CHEM , 10 (2) 527 - 530.

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Abstract

In a search for a mild, rapid, moderately low temperature route to the deposition of thin films of tin(II) sulfide (SnS) on glass, we have investigated the APCVD reaction of tri-n-butyltin trifluoroacetate with hydrogen sulfide at 350-600 degrees C under nitrogen. The films deposited over a 15 min period were shown to be SnS by X-ray diffraction, Raman microscopy, EDAX, SEM and XPS. The conditions established are attractive for the large scale, rapid production of tin(II) sulfide films.

Type:Article
Title:Atmospheric pressure chemical vapour deposition of tin(II) sulfide films on glass substrates from (Bu3SnO2CCF3)-Sn-n with hydrogen sulfide
Keywords:RAY PHOTOELECTRON-SPECTROSCOPY, TIN SULFIDE, THIN-FILMS, PRECURSORS, SELENIDE, SNS, CHALCOGENIDES, CHEMISTRY
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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