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Development of a new photoelectron spectroscopy instrument combining an electrospray ion source and photoelectron imaging

McKay, AR; Sanz, ME; Mooney, CRS; Minns, RS; Gill, EM; Fielding, HH; (2010) Development of a new photoelectron spectroscopy instrument combining an electrospray ion source and photoelectron imaging. REV SCI INSTRUM , 81 (12) , Article 123101. 10.1063/1.3505097.

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Abstract

A new apparatus has been constructed that combines electrospray ionization with a quadrupole mass filter, hexapole ion trap, and velocity-map imaging. The purpose is to record photoelectron images of isolated chromophore anions. To demonstrate the capability of our instrument we have recorded the photodetachment spectra of isolated deprotonated phenol and indole anions. To our knowledge, this is the first time that the photodetachment energy of the deprotonated indole anion has been recorded. (C) 2010 American Institute of Physics. [doi:10.1063/1.3505097]

Type:Article
Title:Development of a new photoelectron spectroscopy instrument combining an electrospray ion source and photoelectron imaging
DOI:10.1063/1.3505097
Keywords:DOUBLE-RESONANCE SPECTROSCOPY, AB-INITIO CALCULATIONS, WATER-CLUSTER ANIONS, GAS-PHASE, MASS-SPECTROMETER, ELECTRONIC SPECTROSCOPY, TRYPTOPHAN PEPTIDES, LASER SPECTROSCOPY, EXCESS ELECTRONS, MOLECULAR-BEAM
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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