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Generation of the ArCF22+ Dication

Lockyear, JF; Douglas, K; Price, SD; Karwowska, M; Fijalkowski, KJ; Grochala, W; Remes, M; (2010) Generation of the ArCF22+ Dication. J PHYS CHEM LETT , 1 (1) 358 - 362. 10.1021/jz900274p.

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Abstract

Thermal reactions of the CF32+ dication with argon lead to the formation of an ArCF22+ dication, a new type of metastable species with an argon carbon bond. None of the other rare gases undergo a similar reaction with CF32+. For the lighter rare gases (He and Ne), no reactions with CF32+ other than those due to electronically excited reactant ions are observed, whereas for the heavier rare gases (Kr and Xe), the prevailing reactive pathways involve single-electron transfer. At elevated collision energies, single-electron transfer predominates for collisions with all rare gases (He-Xe).

Type: Article
Title: Generation of the ArCF22+ Dication
DOI: 10.1021/jz900274p
Keywords: BOND-FORMING REACTIONS, ELECTRON-TRANSFER REACTIONS, GAS-PHASE, MOLECULAR DICATIONS, CHEMICAL-REACTIONS, SIF32+ DICATION, COVALENT RADII, RARE-GASES, CF32+, IONIZATION
UCL classification: UCL > School of BEAMS > Faculty of Maths and Physical Sciences
UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry
URI: http://discovery.ucl.ac.uk/id/eprint/1298337
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