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Functionalised dithiocarbamate complexes: Synthesis and molecular structures of bis(2-methoxyethyl)dithiocarbamate complexes [M{S2CN(CH2CH2OMe)(2)}(2)] (M = Ni, Cu, Zn) and [Cu{S2CN(CH2CH2OMe)(2)}(2)][ClO4]

Hogarth, G; Rainford-Brent, EJCRCR; Richards, I; (2009) Functionalised dithiocarbamate complexes: Synthesis and molecular structures of bis(2-methoxyethyl)dithiocarbamate complexes [M{S2CN(CH2CH2OMe)(2)}(2)] (M = Ni, Cu, Zn) and [Cu{S2CN(CH2CH2OMe)(2)}(2)][ClO4]. INORG CHIM ACTA , 362 (4) 1361 - 1364. 10.1016/j.ica.2008.05.010.

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Abstract

The bis(2-methoxyethyl)dithiocarbamate complexes [M{S2CN(CH2CH2OMe)(2)}(2)] (M = Ni, Cu, Zn, Pd) are readily prepared and the three lighter complexes have been crystallographically characterised. Disproportionation of [Cu{S2CN(CH2CH2OMe)(2)}(2)] upon addition of Cu(ClO4)(2) center dot 6H(2)O affords the copper(III) complex [Cu{S2CN(CH2CH2OMe)(2)}(2)][ClO4] which has also been crystallographically characterised. Unlike other copper(III) dithiocarbamate salts, there are no intermolecular cation-cation or cation-anion interactions. (C) 2008 Elsevier B.V. All rights reserved.

Type:Article
Title:Functionalised dithiocarbamate complexes: Synthesis and molecular structures of bis(2-methoxyethyl)dithiocarbamate complexes [M{S2CN(CH2CH2OMe)(2)}(2)] (M = Ni, Cu, Zn) and [Cu{S2CN(CH2CH2OMe)(2)}(2)][ClO4]
DOI:10.1016/j.ica.2008.05.010
Keywords:Dithiocarbamate, Crystal structures, Methoxy, Copper(III), CRYSTAL-STRUCTURE, MACROCYCLES, TRANSITION, DISPROPORTIONATION, COPPER(III), CRYPTANDS, EXAMPLE, LIGAND
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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