Caddick, S and Hamza, D and Judd, DB and Reich, MT and Wadman, SN and Wilden, JD (2004) A novel route to functionalized PFP esters via rapid intermolecular radical addition to PFP acrylate mediated by ethylpiperidinium hypophosphite (EPHP). TETRAHEDRON LETT , 45 (11) 2363 - 2366. 10.1016/j.tetlet.2004.01.082.
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Abstract
Pentafluorophenyl (PFP) acrylate, a stable compact bifunctional scaffold undergoes rapid N-ethylpiperidinium hypophosphite (EPHP) mediated conjugate radical addition to yield a variety of active esters susceptible to further functionalization by aminolysis. (C) 2004 Published by Elsevier Ltd.
| Type: | Article |
|---|---|
| Title: | A novel route to functionalized PFP esters via rapid intermolecular radical addition to PFP acrylate mediated by ethylpiperidinium hypophosphite (EPHP) |
| DOI: | 10.1016/j.tetlet.2004.01.082 |
| Keywords: | EPHP, radical, addition, amides, PFP esters, CARBON BOND FORMATION, STEREOSELECTIVE-SYNTHESIS, ORGANIC-SYNTHESIS, TIN HYDRIDES, C-GLYCOSIDES, ACID, REAGENTS, ALKENES, DESIGN |
| UCL classification: | UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry UCL > VP Enterprise |
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