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Thioepoxide formation by ring closure of allylthiyl radicals - a novel rearrangement of allylic thionitrites

Cavero, M; Motherwell, WB; Potier, P; Weibel, JM; (2002) Thioepoxide formation by ring closure of allylthiyl radicals - a novel rearrangement of allylic thionitrites. CHEM COMMUN (20) 2394 - 2395. 10.1039/b207252c.

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Abstract

Tertiary allylic thionitrites undergo thermal rearrangement to alpha,beta-episulfide nitroso dimers via ring closure of allylthiyl radicals.

Type:Article
Title:Thioepoxide formation by ring closure of allylthiyl radicals - a novel rearrangement of allylic thionitrites
DOI:10.1039/b207252c
Keywords:INDUCED EPOXIDE FRAGMENTATION, NITRIC-OXIDE, OXIRANYLCARBINYL RADICALS, INTRAMOLECULAR ADDITION, INDUCED DECOMPOSITION, ALPHA-IODOEPOXIDES, CONVENIENT METHOD, ATOM ABSTRACTION, ALKOXY RADICALS, ALKYL RADICALS
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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