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The trifluoromethylacetophenone-N,N-dimethyltrimethylsilylamine adduct - A new shelf stable reagent for nucleophilic trifluoromethylation.

Motherwell, WB; Storey, LJ; (2002) The trifluoromethylacetophenone-N,N-dimethyltrimethylsilylamine adduct - A new shelf stable reagent for nucleophilic trifluoromethylation. SYNLETT (4) 646 - 648.

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Abstract

The simple thermal addition product of N,N-dimethyltrimethylsilylamine with trifluoromethylacetophenone provides a shelf-stable reagent for nucleophilic trifluoromethylation of the carbonyl group.

Type: Article
Title: The trifluoromethylacetophenone-N,N-dimethyltrimethylsilylamine adduct - A new shelf stable reagent for nucleophilic trifluoromethylation.
Keywords: nucleophilic trifluoromethylation, trifluoromethyl carbinols, aldehydes, ketones, EFFICIENT PRECURSOR, FLUOROFORM, ALDEHYDES, KETONES, (TRIFLUOROMETHYL)TRIMETHYLSILANE, CHEMISTRY, BASE
UCL classification: UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry
URI: http://discovery.ucl.ac.uk/id/eprint/129224
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