Motherwell, WB; Storey, LJ; (2002) The trifluoromethylacetophenone-N,N-dimethyltrimethylsilylamine adduct - A new shelf stable reagent for nucleophilic trifluoromethylation. SYNLETT (4) 646 - 648.
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The simple thermal addition product of N,N-dimethyltrimethylsilylamine with trifluoromethylacetophenone provides a shelf-stable reagent for nucleophilic trifluoromethylation of the carbonyl group.
|Title:||The trifluoromethylacetophenone-N,N-dimethyltrimethylsilylamine adduct - A new shelf stable reagent for nucleophilic trifluoromethylation.|
|Keywords:||nucleophilic trifluoromethylation, trifluoromethyl carbinols, aldehydes, ketones, EFFICIENT PRECURSOR, FLUOROFORM, ALDEHYDES, KETONES, (TRIFLUOROMETHYL)TRIMETHYLSILANE, CHEMISTRY, BASE|
|UCL classification:||UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry|
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