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Replacement of imido by disulfido at the molybdenum(VI) centre: reactivity of bis(imido) complexes [Mo(eta(2)-S2CNEt2)(2)(NR)(2)] with hydrogen sulfide and Lawesson's reagent: X-ray crystal structure of [Mo(eta(2)-S2CNEt2)(2)(eta(2)-S-2)(N-2,6-Cl2C6H3)]

Coffey, TA; Hogarth, G; Redmond, SP; (2000) Replacement of imido by disulfido at the molybdenum(VI) centre: reactivity of bis(imido) complexes [Mo(eta(2)-S2CNEt2)(2)(NR)(2)] with hydrogen sulfide and Lawesson's reagent: X-ray crystal structure of [Mo(eta(2)-S2CNEt2)(2)(eta(2)-S-2)(N-2,6-Cl2C6H3)]. INORG CHIM ACTA , 308 (1-2) 155 - 159.

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Abstract

Replacement of imido by disulfido at the molybdenum(VI) centre: reactivity of bis(imido) complexes [Mo(eta (2)-S2CNEt2)(2)(NR)(2)] with hydrogen sulfide and Lawesson's reagent: X-ray crystal structure of [Mo(eta (2)-S2CNEt2)(2)(eta (2)-S-2)(N-2,6-Cl2C6H3)].

Type: Article
Title: Replacement of imido by disulfido at the molybdenum(VI) centre: reactivity of bis(imido) complexes [Mo(eta(2)-S2CNEt2)(2)(NR)(2)] with hydrogen sulfide and Lawesson's reagent: X-ray crystal structure of [Mo(eta(2)-S2CNEt2)(2)(eta(2)-S-2)(N-2,6-Cl2C6H3)]
Keywords: crystal structures, molybdenum complexes, sulfido complexes, EDTC = S2CNET2, BIS(CYCLOPENTADIENYL)TITANIUM, LIGATION, OXO
UCL classification: UCL > School of BEAMS > Faculty of Maths and Physical Sciences
UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry
URI: http://discovery.ucl.ac.uk/id/eprint/129154
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