Clark, RJH and Firth, S and Sella, A and Miskowski, VM and Hopkins, MD (2000) The nature of the normal modes of [Mo-2(CN)(8)](4-). J CHEM SOC DALTON (17) 2928 - 2932. 10.1039/b004186f.
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Abstract
The (1)(delta -->delta*) resonance-Raman and infrared spectra of [NEt4](4)[Mo-2((CN)-C-13)(8)] have been determined and are compared with those previously reported for the natural-abundance isotopomer. The three totally symmetric resonance-enhanced Raman fundamentals of the C-12 compound in the 300-415 cm(-1) region shift to lower wavenumbers (as, of course, do the nu(CN) bands at ca. 2100 cm(-1)) and change in relative intensity upon C-13 substitution. Normal-coordinate calculations on the two isotopomers of the [Mo-2(CN)(8)](4-) ion reveal that the three modes responsible for the resonance-enhanced Raman bands are strongly mixed and of nu(MoMo), nu(MoC), and lambda(op)(MoCN) parentage, and that their intensities roughly scale with the amount of nu(MoMo) character in the modes.
| Type: | Article |
|---|---|
| Title: | The nature of the normal modes of [Mo-2(CN)(8)](4-) |
| DOI: | 10.1039/b004186f |
| Keywords: | RESONANCE RAMAN-SPECTRA, POTENTIAL CONSTANTS, VIBRATIONAL-SPECTRA, METAL-METAL, COMPLEXES, IONS, OCTACHLORODIRHENATE(III), OCTABROMODIRHENATE(III), DIMETALLAPOLYYNE, SPECTROSCOPY |
| UCL classification: | UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry |
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