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Synthesis and characterization of a homoleptic thiolate complex of titanium(IV)

Carmalt, CJ; Dinnage, CW; Parkin, IP; Steed, JW; (2000) Synthesis and characterization of a homoleptic thiolate complex of titanium(IV). INORG CHEM , 39 (12) 2693 - +. 10.1021/ic991382g.

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Abstract

The reaction of Ti(NEt2)(4) with 10 equiv of PhCH2SH in toluene resulted in the formation of the ionic complex [NEt2H2] [Ti-2(mu-SCH2Ph)(3)(SCH2Ph)(6)]. The X-ray structure of the complex has been determined. The coordination number at each titanium center is 6, and the geometry is approximately octahedral.

Type:Article
Title:Synthesis and characterization of a homoleptic thiolate complex of titanium(IV)
DOI:10.1021/ic991382g
Keywords:FILMS, DEPOSITION, PRECURSORS, CRYSTAL
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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