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Pentanuclear alkoxyaluminium hydrides

Carmalt, CJ; Mileham, JD; White, AJP; Williams, DJ; (2002) Pentanuclear alkoxyaluminium hydrides. NEW J CHEM , 26 (7) 902 - 905. 10.1039/b201773n.

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Abstract

Reaction of [AlH3(OEt2)] ( generated in situ from AlCl3 and 3 equivalents of LiAlH4) with one equivalent of (PrOH)-O-i resulted in the formation of the pentanuclear complex [Al-5(mu(4)-O) (mu-Pr-i)(7)H-6]. Incomplete reaction of AlCl3 and 3 equivalents of LiAlH4, followed by the addition of (PrOH)-O-i, afforded the novel species [Al-5(mu(5)O) (mu-Pr-i)(8)(Cl)H-4]. Both complexes have been structurally characterised.

Type:Article
Title:Pentanuclear alkoxyaluminium hydrides
DOI:10.1039/b201773n
Keywords:CHEMICAL-VAPOR-DEPOSITION, HETEROMETALLIC ALKOXIDES, CRYSTAL-STRUCTURE, THIN-FILMS, PRECURSORS
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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