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Selective Conversion of Alcohols into Alkyl Iodides Using a Thioiminium Salt

Ellwood, AR; Porter, MJ; (2009) Selective Conversion of Alcohols into Alkyl Iodides Using a Thioiminium Salt. J ORG CHEM , 74 (20) 7982 - 7985. 10.1021/jo901415n.

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Abstract

Treatment of a range of primary and secondary alcohols with MeSCH=NMe2+ I- affords the corresponding alkyl iodides in excellent yield with straightforward purification. Selective formation of a primary iodide in the presence of a secondary alcohol can be achieved.

Type: Article
Title: Selective Conversion of Alcohols into Alkyl Iodides Using a Thioiminium Salt
DOI: 10.1021/jo901415n
Keywords: CHLOROTRIMETHYLSILANE SODIUM IODIDE, HYDROXYL-GROUPS, REAGENT SYSTEM, EFFICIENT, HALIDES, REPLACEMENT, HALOGENATION, CONVENIENT, INVERSION, SULFIDES
UCL classification: UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry
URI: http://discovery.ucl.ac.uk/id/eprint/126585
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