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Cyclohexadienyl derivatives of (eta(6)-arene)(hydridotris(pyrazolyl) borato) ruthenium(II) compounds

Bhambri, S; Tocher, DA; (1996) Cyclohexadienyl derivatives of (eta(6)-arene)(hydridotris(pyrazolyl) borato) ruthenium(II) compounds. J ORGANOMET CHEM , 507 (1-2) 291 - 293.

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Abstract

The addition of nucleophiles X(-) (X = H, D, OH, CN) to the complex cation [Ru(eta(6)-C6H6)(Pz(3)BH)](+) proceeds smoothly to give the neutral cyclohexadienyl compounds [Ru(eta(5)-C(6)H(6)X)(Pz(3)BH)] which are identified by NMR spectroscopy and single crystal X-ray diffraction (for X = CN).

Type: Article
Title: Cyclohexadienyl derivatives of (eta(6)-arene)(hydridotris(pyrazolyl) borato) ruthenium(II) compounds
Keywords: ruthenium, arene, hydrido, tris(pyrazolyl)borato, crystal structure, DOUBLE NUCLEOPHILIC-ADDITION, ARENE(PHOSPHANE)METAL COMPLEXES, ETA-5-CYCLOHEXADIENYL COMPLEXES, MOLECULAR-STRUCTURE, (BENZENE)RUTHENIUM(II), REACTIVITY, CRYSTAL, LIGANDS
UCL classification: UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry
URI: http://discovery.ucl.ac.uk/id/eprint/118602
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