UCL logo

UCL Discovery

UCL home » Library Services » Electronic resources » UCL Discovery

Synthesis of unsymmetrical ketones via simple C-H activation of aldehydes and concomitant hydroacylation of vinyl sulfonates

Fitzmaurice, RJ; Ahern, JM; Caddick, S; (2009) Synthesis of unsymmetrical ketones via simple C-H activation of aldehydes and concomitant hydroacylation of vinyl sulfonates. ORG BIOMOL CHEM , 7 (2) 235 - 237. 10.1039/b819235a.

Full text not available from this repository.

Abstract

A new and simple protocol for the direct functionalisation of aldehydes with concomitant conversion into ketones via C-C bond formation has been developed. The reaction effectively enables the direct C-H activation of an aldehyde by mixing of an aldehyde and a vinyl sulfonate under aerobic conditions or using hydrogen peroxide as a sub-stoichiometric reagent.

Type: Article
Title: Synthesis of unsymmetrical ketones via simple C-H activation of aldehydes and concomitant hydroacylation of vinyl sulfonates
DOI: 10.1039/b819235a
Keywords: POLARITY-REVERSAL CATALYST, N-HYDROXYPHTHALIMIDE NHPI, RADICAL-CHAIN ADDITION, INTERMOLECULAR HYDROACYLATION, ACYL RADICALS, ALKENES, SULFONAMIDES, ESTERS, DERIVATIVES, AMINOLYSIS
UCL classification: UCL > School of BEAMS > Faculty of Maths and Physical Sciences
UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry
URI: http://discovery.ucl.ac.uk/id/eprint/114289
Downloads since deposit
0Downloads
Download activity - last month
Download activity - last 12 months
Downloads by country - last 12 months

Archive Staff Only

View Item View Item