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Dioxygen mediated hydroacylation of vinyl sulfonates and sulfones on water

Chudasama, V; Fitzmaurice, RJ; Ahern, JM; Caddick, S; (2010) Dioxygen mediated hydroacylation of vinyl sulfonates and sulfones on water. CHEM COMMUN , 46 (1) 133 - 135. 10.1039/b914563j.

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Abstract

Herein we report a mild, facile method for the preparation of 1,4-keto-sulfonates and sulfones on water. Further synthetic manipulations can result in products that are not readily accessed by hydroacylation of electron rich alkenes.

Type: Article
Title: Dioxygen mediated hydroacylation of vinyl sulfonates and sulfones on water
DOI: 10.1039/b914563j
Keywords: POLARITY-REVERSAL CATALYST, N-HYDROXYPHTHALIMIDE NHPI, RADICAL-CHAIN ADDITION, ORGANIC-REACTIONS, AQUEOUS-MEDIA, ALDEHYDES, REACTIVITY, CHEMISTRY, ALKENES, ESTERS
UCL classification: UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry
UCL > VP Enterprise
URI: http://discovery.ucl.ac.uk/id/eprint/112005
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