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Preparation of some new anomeric carbohydrate difluoromethylene-phosphonates via phosphonyl radical addition to gem-difluoroenol ethers

Herpin, TF; Houlton, JS; Motherwell, WB; Roberts, BP; Weibel, JM; (1996) Preparation of some new anomeric carbohydrate difluoromethylene-phosphonates via phosphonyl radical addition to gem-difluoroenol ethers. CHEM COMMUN (5) 613 - 614.

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Abstract

Generation of a phosphonyl radical either from diethyl phosphite, or diethyl (phenylselenyl)phosphonate in conjunction with tributylstannane, in the presence of a carbohydrate gem-difluoroenol ether provides a new route to anomeric difluoromethylenephosphonates; in the course of these reactions, some unusual stereochemical effects are observed.

Type:Article
Title:Preparation of some new anomeric carbohydrate difluoromethylene-phosphonates via phosphonyl radical addition to gem-difluoroenol ethers
Keywords:ELECTRON-SPIN RESONANCE, ANALOGS, ACID
UCL classification:UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Chemistry

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