DISSOCIATIVE RECOMBINATION WITHOUT CURVE CROSSING - STUDY OF HEH+.
J PHYS B-AT MOL OPT
5943 - 5953.
We present a new theory for calculating dissociative recombination (and dissociative attachment) cross sections applicable for systems with or without curve crossings. The theory uses the R-matrix method to build up N + 1 electron 'curves' in an inner region which can be coupled in a full non-adiabatic treatment. We report the first ab initio determination of the low-energy dissociative recombination cross section for (HeH+)-He-4. The cross section is found to be in good agreement with measurements, now disputed, made in a merged beam experiment.
|Title:||DISSOCIATIVE RECOMBINATION WITHOUT CURVE CROSSING - STUDY OF HEH+|
|Keywords:||VIBRATIONAL-EXCITATION, ELECTRON-SCATTERING, COLLISIONS, MOLECULES, GENERATION, ATTACHMENT, ORBITALS, STATES, H-2+, HCL|
|UCL classification:||UCL > School of BEAMS
UCL > School of BEAMS > Faculty of Maths and Physical Sciences
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