UCL logo

UCL Discovery

UCL home » Library Services » Electronic resources » UCL Discovery

The incompressibility and thermal expansivity of D2O ice II determined by powder neutron diffraction

Fortes, AD; Wood, IG; Alfredsson, M; Vocadlo, L; Knight, KS; (2005) The incompressibility and thermal expansivity of D2O ice II determined by powder neutron diffraction. J APPL CRYSTALLOGR , 38 612 - 618. 10.1107/S0021889805014226.

Full text not available from this repository.

Abstract

Using high-resolution neutron powder diffraction, the molar volume of a pure sample of D2O ice II has been measured, within its stability field, at 225 K, over the pressure range 0.25 < P < 0.45 GPa. Ar gas was used as the pressure medium, to avoid the formation of 'stuffed ice' gas hydrates encountered when using He. The third-order Birch - Murnaghan equation of state parameters of helium-free D2O ice II, referenced to 225 K, are: V-0,V-225 = 306.95 +/- 0.04 angstrom(3) ( 1299.7 +/- 0.2 kg m(-3)), K-0,K-225 = 12.13 +/- 0.07 GPa, with K'(0.225) fixed at 6.0. The thermal expansivity of metastable D2O ice II samples recovered to ambient pressure has also been measured, over the range 4.2 < T < 160 K; above 160 K an irreversible transition to ice Ic was observed. The volumetric expansion coefficient, alpha(V), at P = 0 and T = 225 K, is predicted to be 2.48 x 10(-4) K-1.

Type: Article
Title: The incompressibility and thermal expansivity of D2O ice II determined by powder neutron diffraction
DOI: 10.1107/S0021889805014226
Keywords: PHASE-DIAGRAM, HIGH-PRESSURE, CRYSTAL-STRUCTURE, INFRARED SPECTRA, X-RAY, WATER, TEMPERATURE, IH, TRANSITIONS, STABILITY
UCL classification: UCL > School of BEAMS > Faculty of Maths and Physical Sciences
UCL > School of BEAMS > Faculty of Maths and Physical Sciences > Earth Sciences
URI: http://discovery.ucl.ac.uk/id/eprint/100073
Downloads since deposit
0Downloads
Download activity - last month
Download activity - last 12 months
Downloads by country - last 12 months

Archive Staff Only

View Item View Item